---
title: "Meaning & Key Takeaway of: In far from equilibrium conditions, the…"
description: "\"In far from equilibrium conditions, the concept of probability that underlies Boltzmann's order principle is no longer valid if the structures we obser..."
image: "https://sms4smile.com/quotes/i/6cf/ilya-prigogine-30010_complexion_in-far-from-equilibrium-conditions-the-c_1674681.png"
---

#  In far from equilibrium conditions, the concept of…

![“In far from equilibrium conditions, the concept of probability that underlies Boltzmann's order principle is no longer valid if the structures we observe do not correspond to a maximum of complexions” quote by Ilya Prigogine](https://sms4smile.com/quotes/i/6cf/ilya-prigogine-30010_complexion_in-far-from-equilibrium-conditions-the-c_1674681.png)   [Download](https://sms4smile.com/quotes/i/6cf/ilya-prigogine-30010_complexion_in-far-from-equilibrium-conditions-the-c_1674681.png) [Open image](https://sms4smile.com/quotes/i/6cf/ilya-prigogine-30010_complexion_in-far-from-equilibrium-conditions-the-c_1674681.png)

> “In far from equilibrium conditions, the concept of probability that underlies Boltzmann's order principle is no longer valid if the structures we observe do not correspond to a maximum of complexions”

[Ilya Prigogine](https://sms4smile.com/quotes/author/ilya-prigogine/)

## About This Quote

This interpretation was drafted with AI assistance. It is one reading of the quote, not the author's own explanation.

Traditional equilibrium probability fails for far‑from‑equilibrium systems where observed structures are not at maximal microstate counts.

**In simple terms:** Probability concepts break down outside equilibrium.

Key Takeaway

Recognize limits of equilibrium assumptions.

Themes

thermodynamics complex systems entropy

Mood

analytical cautious

Type

theoretical scientific

When to use this quote

- chemical reactions
- climate modeling
- financial markets
- biological development

Key Concepts

Non‑equilibrium self‑organization fluctuation theorems

Questions to Reflect On

- How do you identify when equilibrium assumptions fail?
- What alternative frameworks can capture observed structures?

A Different Perspective

Equilibrium models may still offer useful approximations.

★ ★ ★ ★ ★   No ratings yet

[Boltzmann](https://sms4smile.com/quotes/about/boltzmann-895837/) [Boltzmann Order](https://sms4smile.com/quotes/about/boltzmann-order-895835/) [Complexion](https://sms4smile.com/quotes/about/complexion/) [Concepts](https://sms4smile.com/quotes/about/concepts/) [Conditions](https://sms4smile.com/quotes/about/conditions/) [Equilibrium](https://sms4smile.com/quotes/about/equilibrium/) [Far Equilibrium](https://sms4smile.com/quotes/about/far-equilibrium-895838/) [Ifs](https://sms4smile.com/quotes/about/ifs/) [Maximum](https://sms4smile.com/quotes/about/maximum/) [Order](https://sms4smile.com/quotes/about/order/) [Order Principle](https://sms4smile.com/quotes/about/order-principle-895839/) [Principles](https://sms4smile.com/quotes/about/principles/) [Probability](https://sms4smile.com/quotes/about/probability/) [Structure](https://sms4smile.com/quotes/about/structure/) [Underlies Boltzmann](https://sms4smile.com/quotes/about/underlies-boltzmann-895836/)

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